D polyolefin plastic thermoplastic blend of partially cured monoolefin copolymer rubber an

ABSTRACT

Thermoplastic blends of partially cured monoolefin copolymer rubber (such as EPM or EPDM rubber) with a polyolefin resin (such as polypropylene) exhibit good physical properties and are reprocessable. The partial cure of the rubber is effected by heating the rubber with a curative such as a peroxide. The blends are used to make molded or extruded articles which have good physical properties without requiring vulcanization; preferred blends have the characteristics of thermoplastic elastomers.

United States Patent 1 1 Fischer [451 Sept. 11,1973

[75] Inventor: William K. Fischer, Woodbury,

Conn.

[73] Assignee: Uniroyal, Inc., New York, N.Y.

[22] Filed: Jan. 20, 1971 [21] Appl. No.: 108,225

[52] U.S. Cl..... 260/897 A, 260/45.7 P, 260/79.5 B,

260/79.5 P, 260/80.78, 260/88.25 [51] Int. Cl C081 29/12, C08f 37/18 [58] Field of Search 260/8 97 [56] References Cited UNITED STATES PATENTS 3,256,366 6/1966 Corbelli 260/897 3,218,373 11/1965 Salyer 260/878 3,564,080 2/1971 Pedretti et a1. 260/897 3,203,937 8/1965 Breslow et al. 260/79.3

FOREIGN PATENTS OR APPLICATIONS 1,043,078 9/1966 Great Britain 260/897 798,416 11/1968 Canada ..260/897 Primary Examiner-Murray Tillman Assistant Examiner-C. J. Seccuro Attorney-James J. Long [5 7 ABSTRACT Thermoplastic blends of partially cured monoolefin copolymer rubber (such as EPM or EPDM rubber) with a polyolefin resin (such as polypropylene) exhibit good physical properties and are reprocessable. The partial cure of the rubber is effected by heating the rubber with a curative such as a peroxide. The blends are used to make molded or extruded articles which have good physical properties without requiring vulcanization; preferred blends have the characteristics of thermoplastic elastomers.

45 Claims, No Drawings THERMOPLASTIC BLEND OF PARTIALLY CURED MONOOLEFIN COPOLYMER RUBBER AND POLYOLEFIN PLASTIC This invention relates to a thermoplastic blend and a method of making same.

Thermoplastic elastomers, which can be processed and fabricated by methods used for thermoplastics and do not require vulcanization to develop elastomeric properties, are known (see, for example, U.S. Pat. No. 3,265,765, Holden et al., Aug. 9, 1966; also Hartman et al., Butyl Grafted to Polyethylene yields Thermoplastic Elastomer Rubber World, Oct., 1970, pages 59-64). Conventionally these materials have been made by special block copolymerization or polymer grafting methods. The present invention is based on the discovery that a thermoplastic elastomeric composition can be made by blending a certain rubber and resin.

Blends of monoolefin copolymers with polyolefins have been known (e.g., U.S. Pat. Nos. 3,256,366 Corbelli et al., June 14, 1966 and 3,456,038 Newman et al., July 15, 1969; British patent 1,043,078, Phillips Petroleum Co., Sept. 21, 1966; Canadian patents 789,074 Brender et al., July 2, 1968 and 792,277, Schreiber, Aug. 13, 1968; Belgian patent 731,950, Sumitomo Chemical Co., Oct. 23, 1969, etc.), but those blends have not had the characteristics of thermoplastic elastomers.

The present invention is based on the discovery that a thermoplastic blend having highly desirable characteristics is provided by a partially cured rubber in admixture with a resin. More particularly, the invention is based on a blend of partially cured monoolefin copolymer rubber and polyolefin plastic, which blend is thermoplastic and can be fabricated by such methods as molding and extrusion, into shaped articles, which do not require a vulcanization step to develop good physical properties. The invention thus provides thermoplastic elastomers which can be molded or otherwise shaped without necessity for performing an expensive and time-consuming vulcanization step in the shaped article. Furthermore the blends can be reprocessed, just like a typical thermoplastic material.

lnaccordance with the invention the monoolefin cpolymer rubber, typified by saturated EPM (ethylene- 45 propylene copolymer rubber) or unsaturated'EPDM (ethylene-propylene-non-conjugated diene terpolymer rubber), is partially cured by the action of a conven-' tional curing agent. The curing conditions are such that the cure of the rubber is only partial, that is,.the rubber is not cross-linked'to the state where it becomes almost entirely insoluble in the usual solvents for the uncured rubber. It has been found that monoolefin rubber which has thus been partially cured or crosslinlted,provides, in admixture with a poly-olefin plastic, a thermoplastic material having the herein describe unusual combination of desirable characteristics.

In carrying out the invention the monoolefin copolymer rubber component of the blend is firstmixed with a small amount of curative, and subjected to curing conditions. The amount of curative and the curing conditions are so selected as to produce only a partial cure of the rubber as evidenced by conventional. tests suitable for determining the degree of cure or cross-linking of an elastomer, such as various solubility and swelling tests, including conventional gel determinations, tests for cross-link density, tests for combined sulfur when sulfur cures are used, and the like. Another method for determining a partial state of cure is to observe whether the material processes on a mill to form a continuous band or whether it fails to knit, which would indicate 5 over-curing. The blend of the invention is provided by mixing the partially cured monoolefin rubber with a polyolefin plastic.

The monoolefin copolymer rubber employed in the blend of the invention is an amorphous, random, elastomeric copolymer of two or more monoolefins, with or without a copolymerizable polyene. Usually two monoolefins are used, but three or more may be used. Ordinarily one of the monoolefins is ethylene while the other is preferably propylene. However other alpha- 5 monoolefins may be used including those of the formula CH CHR where R is an alkyl radical having for example one to 12 carbon atoms (e.g., butene-l, pentene-I, hexene-l, 4-methylpentene-l, 5-methylhexene- 1, 4-e'thylhexene-1, etc.). While the monoolefin copolymer rubber may be a saturated material, as in ehty- 0 as 1,4 -hexadiene (U.S. Pat. No. 2,933,480 Gresham et' al., Apr. 19, 1960) or a cyclic diene, especially a bridged ring cyclic diene, as in dicyclopentadiene (U.S. Pat. No. 3,211,709,,Adamek et al., Oct. 12, 1965),'or an alkyl-idenenorbornene as in methylenenorbornene or-ethylidenenorbornene (U.S. Pat. No. 3,151,173,

Nyce, Sept. 29, 1964), as well as cycloctadiene, methyltetrahydroindene, etc. (see also such U.S. Pats. Nos. as 3,093,620 and 3,093,621; also 3,538,192 col. 6, line 49 to col. 7, line 51). The polyenes employed are not limited to those having only twodouble bonds, but include those having three or more double bonds. 7 Y The polyolefin resin with which the semi-cured monoolefin copolymer rubber is mixed to make the blendof the invention is a solid, high molecular weight resinous plastic material made by polymerizing such olefins as ethylene, propylene, butene-l, pentene-l', 4-

methyl-pentene, etc., in conventional manner. Thus, such crystalline polyolefins as polyethylene (either of o the low density [e.g., 1910-.925 g/cc], medium density 1.926 940 g/cc] or high density [e.g., 0.941-01965 g/ccjltype) may be used, whether prepared by high pressure processes or low pressure processes, including linear polyethylene. Polypropylene is a preferred polyole'fin plastic, having highly crystalline isotactic and syndiotactic forms. Frequently the density of polypropylene is from 0.800 to 0.980 g/cc. Largely isotactic polypropylene having a densityof from 0.900 to 0.910

g/cc may be mentioned-particularly. Crystalline blockcopolymers of ethylene and propylene (which are plas- ,tics distinguished from amorphous,.random ethylenepropylene elastomers) can also be used. Included among the polyolefin resins are the higher alpha-olefin modified polyethylene s and polypropylenes (see Polyolefins," N.V. Boenig, Elsevier Publishing Co., N.Y., 1966 v 1 Therelative proportions of partiallyv cured monoolefin copolymer rubber and polyolefin plastic employed in the blends of the invention may vary widely, for example from to 90 parts by weight of partially cured mono-olefin copolymer rubber and correspondingly 90 to 10 parts of polyolefin plastic, depending on the characteristics desired in the blends. Of particular importance are the blends having an elastomeric character, containing a major proportion of the partially cured monoolefin co-polymer rubber, usually 50 to 90 parts of the semi-cured rubber, more preferably 60 to 80 parts, per 100 parts by weight of the blend of rubber and plastic.

As indicated, an important feature of the invention resides in semi-curing the monoolefin copolymer rubber to be mixed with the polyolefin plastic. For this purpose any conventional curative may be employed, incuding such free-radical generating agents or crosslinking agents as the peroxides, whether aromatic or aliphatic as in the aromatic diacyl peroxides and aliphatic diacyl peroxides, dibasic acid peroxides, ketone peroxides, alkyl peroxyesters, alkyl hydroperoxides, e.g., diacetylperoxide, dibenzoylperoxide, bis-2,4- dichlorobenzoyl peroxide, di-te'rt.-butyl peroxide, dicumylperoxide, tert.-butylperbenzoate, tert.-butylcumyl peroxide, 2,5-bis (tert.-butylperoxy)-2,5- dimethylhexane, 2,5-bis-(tert.-butylperoxy)-2,5-dimethylhexyne-3; 4,4,4',4'-tetra-(tert.-butylperoxy)-2,2- dicyclohexylpropane, l,4-bis-(tert.-butylperoxyisopropyl)-benzene, l,l-bis-(tert.-butylperoxy)-3,3,5- trimethylcyclohexane, lauroyl peroxide, succinic acid peroxide, cyclohexanone peroxide, tert.-butyl peracetate, butyl hydroperoxide, etc. Also suitable are the azide types of curing agents including such materials as the azidofomates [e.g., tetramethylenebis(azidoformate); for others see U.S. Pat. No. 3,284,421, Breslow, Nov. 8, 1966], aromatic polyazides (e.g. 4,4- diphenylmethan diazide; for others see U.S. Pat. No. 3,297,674, Breslow et al., Jan. 10, 1967), and sulfonazides such as p,p'-oxybis (benzene sulfonyl azide), etc. Other curatives that may be used include the aldehydeamine reaction products such as formaldehydeammonia, formaldehyde-ethylchloride ammonia, acetaldehyde-ammonia, formaldehyde-aniline, butyraldehyde-aniline, heptaldehyde-aniline, heptaldehyde-formaldehyde-aniline, hexamethylenetetramine, alphaethyl-beta-propylacrolein-aniline; the substituted ureas [e.g., trimethylthiourea, diethylthiourea, dibutylthiourea, tripentylthiourea, l,3-bis(2-benzothiazolylmercaptomethyl) urea, and N,N-diphenylthiourea]; guanidines (e.g., diphenylguanidine, di-otolylguandine, diphenylguanidine phthalate, and di-otolylguanidine salt of dicatechol borate); xanthates (e.g., zinc ethylxanthate, sodium isopropylxanthate, butylxanthic disulfide, potassium isopropylxanthate, and zinc butylxanthate; dithiocarbamates (e.g., copper dimethyI-,zinc dimethyl-, tellurium diethyl-, cadmium dicyclohcxyl-, lead dimethyl-, selenium dibutyl-, zinc pentamethylene-, zinc didecyl-, and zinc isopropyloctyl-, dithiocarbamate); thiazoles [e.g., Z-mercaptobenzothiazole; zinc mercaptothiazolyl mercaptide, 2- benzothiazolyl-N,N-diethylthiocarbamyl sulfide, and 2,2'-dithiobis (benzothiazole)]; imidazoles (e.g., 2- mercaptoimidazoline and 2-mercapto-4,4,6-trimethyldihydropyrimidine); sulfenamides (e.g., N-t-butyl-Z- benz0thiazole-, N-cycl0hexylbenzothiazole-, N,N- diisopropylbenzothiaz0le-, N-(2,6- dimethylmorpholino)-2-benzothiazole-, and N,N-

diethylbenzothiazole-sulfenamide]; thiuramidisulfides 4 (e.g., N,N'-diethyl-, tetrabutyl-, N,N' -di-isopropyldioctyl-, tetramethyl-, N,N'-dicyclohexyl-, and N,N'- tetralaurylthiuramdisulfide); also paraquinonedioxime, dibenzoparaquinonedioxime, etc. as well as sulfur itself (see Encyclopedia of Chemica Technology, Vol.

17, 2nd edition, lnterscience Publishers, 1968; also Organic Peroxides, Daniel Severn, Vol. 1, Wileylnterscience, 1970). The peroxide curative may be used alone, or in conjunction with the usual auxilliary substances such as sulfur, maleimides including bismaleimides, poly-unsaturated compounds (e.g., cyanurate), acrylic esters (e.g., trimethylolpropanetrimethacrylate), etc. With sulfur curatives, such as sulfur itself or sulfur donors, it is usually desirable to include an accelerator-of sulfur vulcanization as well as an activator (e.g., a metal salt or oxide), as in conventional practice. Mixed peroxide-type or mixed sulfur-type curing systems may be employed if desired such as dicumylperoxide plus 2,5-bis(tert.-butylperoxy)-2,5- dimethylhexane or sulfur plus tetramethylthiuramdisulfide. The preferred monoolefin copolymers having residual unsaturation, conferred by the presence of a polyene, such as EPDM, afford the widest choice of curatives. Reference may be had to Vulcanization and Vulcanizing Agents, W. Hoffman, Palmerton Publishing Co., New York, 1967, for an extensive disclosure of curing agents.

In accordance with the invention, the amount of cure or cross-linking imparted to the monoolefin copolymer rubber component of the blend is only partial, as distinguished from a full or substantially complete cure or cross-linking. As indicated, various tests for cure or degree of cross-linking may be applied, one of the more convenient tests being the content of gel or insoluble material. For purposes of the invention, the gel content of the semi-cured or partially cross-linked monoolefin copolymer rubber should be substantiallyin excess of the gel content of the original rubber prior to the partial curing step. Thus, the gel content of "the partially cured monoolefin copolymer rubber, measured in cyclohexane, will ordinarily be at least 10 percent in excess of the original gel content of the rubber, preferably at least 20 percent in excess, and more preferably at least 30 percent in excess of the gel content of the origigel is of course the portion of the rubber that is insolu-= ble in the specified solvent, in this case cyclohexane, and is conveniently measured by immersing a sampleof the material in the solvent for 48 hours at 73F, taking an aliquot of the solution and determining the concentration of solute by evaporating .the solvent. lt will be understood that with other solvents at other tempera tures, the gel value of a particular sample-may be differ ent. Thus, measured in boiling xylene the gel values of the present semi-cured monoolefin copolymer, rubber would ordinarily be very much lower than (e.g., 30-40 percent lower) the given gel values incy'clohexane at- The gel formed as a result of the described cross linking treatment typically has a much lower swelling index than gelsometimes found in the original, un-

treated mono-olefin copolymer rubber. Typically the percent swell of the cyclohexane-insoluble gel formed as a result of the present semi-cure is at least 8 percent less, usually 10 percent to 70 percent less, than the percent swell of any gel present originally. Ordinarily the percent swell of the semi-cured monoolefin copolymer rubber is within the range of from 6 to 35 percent. (percent gel and percent swell are elucidated in more detail in US. Pat. No. 3,012,020, Kirk et al., Dec. 5, 1961.)

The desired semi-cure of the monoolefin copolymer rubber is brought about by mixing the rubber with a small amount of the curing or cross-linking agent, and subjecting the mixture of conventional curing conditions. it will be understood that the curing or crosslinking parameters (viz.,, the amount of curing agent, and/or the curing temperature and/or the curing time) will be so selected as to produce a partial or semi-cure, rather than a full or substantially complete cure. Thus, in many cases use of less than two-thirds, or use of less than one-half, and in some cases one-fourth or less, of f the amount of curative conventionally required for full cure, is capable of producing the desired degree of partial cure in the monoolefm copolymer rubber, asevidenced by the development of a gel content in cyclohexane within the described range. Such gel content is distinguished from values of 100 percent gel content in cyclohexane displayed by the'copolymer even before it is fully cured. Fully cured or cross-linked monoolefin copolymer rubber is almost entirely insoluble even in boiling xylene. It will also be understood that fully cured monoolefin copolymer rubber will not form a continuous sheet on a mill, that is, it is not a processable material.

The partial cure of the monoolefin copolymer rubber in admixture with the cross-linking agent may be brought about under dynamic conditions or under static conditions. To effect the semi-cure dynamically, the copolymer-curing agent mix may be worked on an open roll mill, or in an internal mixer (such as a Banbury mixer or an extruder). Frequently, working at a temperature of l60 to 400F for 5 or 10 minutes is sufticient to bring about the desired semi-cure. To effect the semi-cure statically, the copolymer-curing agent mix may be treated for example in an autoclave, for example at a temperature of 160 to 500! for 5 to 30 minutes.

The cross-linking treatment substantially exhausts the action of the curing agent so that .there is little or no tendency for further advancement of cure to take place subsequently. Ordinarily, heating of the rubbercurative mix fora period of time equal to at leastfour half-lives of the peroxide or other curative is desirable. it is sometimes desirable" to insure termination of the action of any remaining cross-linking agent, by adding to the mix, at the end of the partial curing step, a small amount of a free-radical scavenging agent, such as a stabilizer or antioxidant. in the dynamic semi-cure method, such stabilizer may be added and mixed in for the last minute or so of mixing. in the static semi-cure method, after removal of the semi-cured material from the autoclave, the semi-cured material may be subjected to one or more refining passes on amill, and the stabilizer may be added in the course of or just prior to the blending with the poly-olefin plastic. Any conventional antioxidant or stabilizer may be used, including, by way of non limiting example, amine types, phe-' nolic types, sulfides, phenyl alkanes, phosphites, etc.

Representative materials are listed in Rubber: Natural and Synthetic, Stern, Palmerton Publishing Co., New York, i967, of which the disclosure at pages 244-256 is incorporated herein by reference; see also Chemistry and Technology of Rubber Davis & Blake, Reinhold, New York, 1937, Chapter XII. Included are such materials as 2,2,4-trimethyl-l,2-dihydroquinoline, diphenylamine acetone condensate, aldol 'alphanaphthylamine, octylated diphenylamine, N-phenyl-N- cyclohexyl-p-phenylene diamine, 2,6-di.-tert.butyl-4- methyl phenol, styrene-resorcinol resin, o-cresol monosulfide, di-p-cresol-Z-propane, 2,5-di.-tert.-amyl hydroquinone, dilauryl 3,3'-thiodipropionate, etc.

The thus partially cross-linked monoolefin copolymer rubber may be tested for gel content in cyclohexane and/or for processability (band formation on a mill). Such tests will reveal whether the polymer has received insufficient cross-linking on the one hand (gel content too low; swelling index high) or too much cross-linking on the other hand (gel content too high; inability to form a band on a tightly closed low-friction mill in spite of considerable refining). One or two preliminary tests on a small trial batch will usually suffice to establish aproper amount of particular curing agent to employ with 'a specific copolymer under a given set of pre-curing conditions. Appropriate manipulation of the variables may be madeinany given case to produce a satisfactory result, using the working examples below as a guide. I

Although in general the conditions under which the partial cure of the monoolefin copolymer rubber is effected may fall within the ranges of conventional vulcanizing conditions, itwill be understood that care will be taken to limit the'degree of cure, either by using reduced amount of curative and/or reduced durationor severity of thecuring conditions, so that the rubber does not become completely cross-linked but remains at least partially soluble and thermoplastic, as distinguished from an insoluble, thermoset, fully cured rubber which is no longer processable. Although certain curing systems operate at room temperature it is more usual to heatthe monoolefm copolymer containing the curative to bring about partial cure. Moderate heating (e.g. l00 f l 5 0F)is frequently sufficientalthough in some cases considerably higher temperatures (e.g'., 300-500F or moretmay be used in the partial cure. The time. required for the'partial-cure will vary with such'ffactors as the particular copolymer rubber employed, the kind'and amount of curative, and the temperatureat which-the partial cure'is carried out, as well as other factors such as the size of the batch, the character. yof the. heating device employed, whetherthe treatmentis dynamic or static, etc. In general the time is inversely related to the temperature and concentration of curative, and more severe time-temperation conditions may be used in the static method than in the' sary to break the material down slightly by milling, be-

fore it will bandl Thus, if the semi-cured rubber has a gel content in cyclohexane in excess of percent, it

' maybe broken down by'milling until the gel content is less than 90 percent, making it suitable for use in the invention. If the cure has gone beyond the point where the material can be broken down, the material is not suitable. The gel content of the semi-cured rubber at or prior to mixing with the resin should be less than 90 percent.

The thus pro-treated partially cross-linked monoolefin copolymer rubber may be blended with the polyolefin plastic in any appropriate conventional manner, for example on a roll mill, in a Banbury mixer or in an extruder to provide the thermoplastic blend of the invention. The mixing temperature should be sufficient to soften the plastic and form a uniform mix. Pigments, fillers, stabilizers, lubricants, u.v. screening agents, or other appropriate compounding or modifying ingredients may be included in the blend if desired. The-blend of the invention provides a noteworthy combination of processability (including the ability to be reprocessed repeatedly) with good physical characteristics. The good physical characteristics include properties heretofore usually associated only with vulcanized or thermoset (not reprocessable) materials, notably low permanent set. The blends of the invention accordingly afford a way of producing thermo-formed shaped objects (e.g., by extrusion, injection or compression molding) which combine the convenience and speed of thermoplastic shaping with certain physical characteristics of thermoset or vulcanized elastomers.

Heretofore, certain desirable characteristics such as low permanent set have largely been obtainable only in vulcanized elastomers which required the molder to use a rather long dwell time in the mold to effect vulcanization. The vulcanized flash or scrap could not be reprocessed. On the other hand, thermoplastic materials could be molded rapidly and scrap could be reprocessed, but certain physical characteristics such as permanent set were usually rather poor. The present blends of partially pre-cured monoolefin copolymer rubber and polyolefin plastic combine in one material the advantages of rapid moldability and re-processability with the advantages of a vulcanizate (low permanent set).

It will be understood that in many plastic and elastomer shaping operations a considerable percentage of scrap is produced. Examples of this are in dieing out parts from extruded, press-molded or calendered sheet and sprues and runners which result from screw injection molding. Such scrap produced from the blend of the invention may be chopped and re-extruded seven or more times with no significant deterioration in appearance or processing characteristics. The blends, in addition to being reprocessable', have enhanced properties including tensile strength and resistance to compression set, resistance to deterioration in oil, reduced elongation set, and improved resistance to abrasion and flex-cracking.

Useful articles that may be made from the blends of the invention by such methods as extrusion, screwinjection, blow molding, press molding, calendering and vacuum forming include extruded insulation on wire, gaskets, flexible tubing, balls, Weatherstripping, flexible bumpers, etc.

The blend of the invention will of course invariably contain a substantial amount (e.g., at least percent by weight) of each polymer, and the blends of particular interest are those in which the semi-cured monoolefin copolymer rubber constitutes at least half of the blend of the two polymers. The blends containing 50-90 percent (by weight, based onthesum of the weight of the two polymers) predominate in elastomeric properties and are preferred, while with decreasing amounts of partially cured monoolefin copolymer rubber the blends take on more the characteristics of a hard rubber or plastic. If desired, mixtures of EPMs or EPDMs or both may be used with one or more polyolefins.

In comparison to a commercially available thermoplastic elastomer which is a butadiene-styrene block copolymer known as Kraton 3125, blends of the invention have been observed to have higher hardness and, more importantly, much greater retention of hardness when heated to elevated temperatures of 200 or 300F, for example. The heat deflection-upon subjecting to 2,000 grams pressure per square inch for 1 hour at 250F was zero for compositions of the invention, but 67 percent for the conventional block copolymer. The volume change of compositions of the invention after immersion 24 hours at 150Fin fuel B was of the order of 141 to 308 percent, whereas the block copolymer dissolved. In No. 2 oil, the volume change of compositions of the invention was 26-57 percent; the block copolymer changed percent.

As indicated, processability, reprocessability, is an important characteristic of the blends of the invention. The processability of the blends may be evaluated by subjecting samples of the.

blend to such shaping operations as extrusion, injection molding, or compression molding, asdescribed in the working examples below. Extrusion is the shaping method of choice where long continuous forms, such as hose, window seals, wire coatings, flat sheets, etc. are desired. It is important that the extruded article have acceptable surface smoothness. In most cases the'materials of the invention are well adapted to extrusion methods, although in some cases, particularly where the gel level is on the high side, the extruded surfaces may not be as smooth to the touch as desirable. However, even the blends which are not satisfactorily extrudable can usually be shaped by injectionmolding. For satisfactory screw injection molding the material must form in the mold a homogeneous article of uniform strength. The flow viscosity characteristics of such blends are adequate to insurefilling the mold under the operatingconditions.The .most highly semi cured rubbers usually give blends of the invention which are ordinarily best shaped by press molding.

The elastomeric character of objects shaped without vulcanization from blends of the invention is perhaps evidenced most strikingly by the low elongation set at.

break, measured by ASTM D412. In the present preferred elastomeric blends, the'elongation set at-break is usually improved (i.e. decreased) by at least 30 percent, preferably by at least 50 percent. However other physical properties such as tensile strength and ultimate elongation at break are also significant, and the combined effect of these properties is conveniently expressed as a performance factor," P.F., which is defined as follows:

P.F., psi X I0 [(Tensile, psi) X (Elongation, %)/Elongation Set at Break, where the tensile strength and the elongation are measured by method ASTM D412. As will be made manifest in the working examples below, the performance factor" of blends of the invention is improved (increased) by at least 20 percent more frequently by 45 and particularly percent, over the performance factor of otherwise similar blends in which the rubber is notflsemi-cured. In highly preferred blends, the performance factor is increased to two or more times its control value.

The reprocessability of the blendsof the invention is demonstrated by the fact that blends of the invention have been extruded and re-extruded up to seven times and still retained desirable characteristics.

The following examples, in which all parts are expressed by weight, will serve to illustrate the practice of the invention in more detail.

EXAMPLE 1 ln runs summarized in Table I, Part A and Part B an EPDM rubber semi-cured by hot-mastication with a peroxide curative is blended with various polyolefin plastics. The EPDM rubber to polyolefin plastic weight ratio ranges from :90 to 90:10. For comparison, some stocks are included containing no EPDM (Runs I7, 22 and 23); these are outside the invention. The EPDM rubber employed, identified as EPDMI, contains 47.5 percent ethylene, 47.5 percent propylene and 5 percent dicyclopentadiene, by weight; the M00- ney viscosity is 65 (ML-4 at 250F); the gel content of the untreated EPDM is 3 percent (all gel contents expressed herein, unless otherwiseindicatedare measured by immersion in cyclohexane for 48 hours at 73F). The peroxide employed to semi-cure the EPDM, identified as peroxide I, is 2,5-bis (tert-butylperoxy) -2,5-dimethylexane; it has a half-life at 347F of .98 minute; it is employed as a 50 percent active commercial preparation (Varox). For comparison some stocks are included in which no curative is used (Runs l,2,3,l8 and these are outside the invention. The polyolefm plastics employed are polypropylene, high density polyethylene, and low density polyethylene. The polypropylene employed is a largely crystalline, isotactic polypropylene, having a melt flow index of 4.0 (ASTM Dl238-57T, 230C), a specific gravity of 0.903, and 94 percent gel (Profax 6523). The polyethylene identified in Table I as H. D. Polyethylene.

is ahigh density polyethylene having a melt flow index of 0.3 (D1238 E, 190C) a specificvgravity of 0.956, and 90 percent gel (Hifax 4601). Thep'olyethylene identified in Table I as L. D. polyethylene is a low density polyethylene having a melt flow-index of 2.0 (D

1238, 190 C) a specific gravity'of: 0.919, gel content nil (DYNH). Prior to blending theEPDM with the polyolefin resin, the EPDM is mixed with-the indicated amount of peroxide curativeon a'wa rmed mill at a stock temperature usually not higher than .180Fi, and 1 then charged to a Banbury preheated to 240F. The EPDM-peroxide mix is masticateduntil the temperature as read on a chart activated by a thermocouple located on the wall of the mixing chamber indicates a temperature of 360-4l0F (see cure temperature" in Table I). This ordinarily takes about. 2-3 minutes. The mixing is continued at the temperature for an additional 7-8 minutes (cure time" in Table I). The actual stock temperature is usually about 2530F higher. than the chart temperature. One part (per '100 parts of EPDM) of an antioxidant, tris(nonylated phenyl) phosphite, is then added and blended in for 1 minute as a free-radical scavenger. The gel content, percent swell and Mooney viscosity of the thus semi-cured EPDM are then determined with the results shown in Table I.

In the next step of the process the semi-cured EPDM rubber is blended with the polyolefin plastic, in the amounts shown in Table l, in the Banbury mixer. The blending temperature listed in Table I is the maximum chart temperature achieved in the run (the actual stock temperatures are usually some 25 to 30 F higher); the blending time is the length of time for which mixing is continued at that temperature. The blending time for the blends using semi-cured EPDM rubber is about 1. minute, but for-the blends using EPDM rubber that has not been pre-cured (control stocks 1,2,3, 18 and 20) the blending time employed is about 7 minutes. The purpose of this is to essentially equalize the total masticating time at elevated temperature, for better comparison. The thus uniformly mixed blend is thendischarged from the Banbury, formed into a sheet on a mill and chopped into pellets for further evaluation. I

In Table I, the values listed as calculated gel are theoretical gel values of the blend calculated from the known gel contents of the'two components of the blend, assuming no change in gel values of the ingredients in the course of the blending. Also listed are the actual gel values as measured on the blends, as well as the percent swell of the blends. The calculated values are somewhatlessthanthe actual measured gel content; this may be attributed to entrappment or coating of portions of the relatively soluble EPDM by the less soluble polyolefin plastic.

The Mooney viscosities of the blends are also listed in Table I.

Portions of the pelletized blends are screw injection molded into test specimens, on which the physical properties are determined by standard test methods with the results shown in Table I. From the tensile strength, ultimate elongation and elongation set at break results, the value termed the performance factor as defined above is also calculated for each blend, as indicated in Table I.

The extrudability results listed in Table I are determined on a Brabender extruder (Type EX3A, No. 191) under the following conditions: screw, compression ratio 2/l. s crew speed 20 rpm, temperature at rear of barrel '375F, temperature at front of barrel 400F, die diameter one-eighth inch,.temperature of die 420F.

The material is considered extrudable if the extrudate feels smooth to the touch, otherwise it is not.

The injection molding results listed in'Table I are obtained by forming test pieces in an Ankerwerke screw injection: molding machine (Model 75, Serial No. l207'l,"capacity 2 oz.-), usinga rear barrel temperature of 375F, 'a front barrel temperature of 400F., a nozzle temperature of 420F and a mold temperature of 100F. The injection time is 3 seconds, holding timelOseconds, and totalcycle time is 30' seconds. The screw back pressure is 200 psi, screw speed High, in-

' jection speed setting of and maximum injection pressure is 1000 psi. The dimensions of the mold cavity are 2 X6 X0075 inches. The injection molded samples are evaluated'by observing whether the formed specimen is homogenous, e.g., without cracks, and of uniform strength indicating that the compositions have the percent to values within the range from 58 to 87 percent, while the swell of the rubber decreases dramatically; also the Mooney viscosity increases. Thesechanges are indicative of partial cure or cross-linking of the EPDM rubber.

Comparison of blends of the EPDM rubber, with and without semi-cure, with polyolefin plastic at the same ratio, vis., comparison of Run 1 (80:20 ratio, no precure) with Run 6 (80-20 ratio, with senii-cure) shows that the blend based on semi-cured EPDM (Run 6) not only has higher actual gel, lower swelling index and higher Mooney viscosity, but, more significantly, has greatly reduced elongation set at break, and a performance factor increase of more than 300 percent, while retaining good processability asevidenced by the fact that it is extrudable and moldable. Thus, perfor-. mance comparable to a vulcanized rubber is provided while retaining the processability of athermoplastic material. It will be understood that no vulcanization or cure of the material takes place during the molding of the test specimens (the action of the peroxide curative having been essentially exhausted in the pre-curing step and any residual free radicals having been scavenged by the antioxidant) and the molded or extruded specimens remain thermoplastic and repeatedly reprocessable.

Similarly the other blends of the invention exempli-- fied exhibit desirable decrease in elongation set at break, and increase in performance factor, while retaining thermoplastic reprocessability.

In the foregoing example, polypropylene resin having a melt flow index of'O.8 (D 1238 L, 190C), a specific gravity of 0.903 and 99 percent gel (Profax 6723"), may be substituted. Dicumyloperoxide (Dicup may be substituted as the peroxide curative.

TABLE I.-PART A BLENDS OF EPDM WITH POLYOLEFIN PLASTICS Run N o.

EPDM I, pts 100 100 100 100 100 100 100 100 100 100 100 100 Peroxide I, pts 75 875 625 875 .75 875 75 875 1. 0 Peroxide, moles X10=/100 g. EPDM-. 2 9 3 4 2 4 3.4 2.9 3.4 2 9 3 4 3.9 Cure temp. F., max 360 360 410 360 360 360 360 360 360 Cure time, minutes- 8 8 7 8 g 8 8 8 7 Gel, percent 3 3 3 68 73 58 65 58 65 82 Swell, percent..- 62 62 62 12 12 21 12 12 12 12 12 13 65 65 65 MS-4 at 250 F 47 60 53 40 53 40 63 Masterbatch (EPDM), pts 70 60 90 8O 80 70 70 60 60 60 Polypropylene, pts 20 30 4O 10 20 20 30 30 40 40 40 H.D. polyethylene, pts

L.D. polyethylene, pts. Blending Temp. F., ma Blending time, minutes at temp Cale. gel, percent Tensile strength, p.s.i modulus, p.s.l Elongation, percent Elongation set at break, percent- Hardness, shore A ble Injection moldable Press moldeble Yes Yes Yes Yes Yes Yes Yes TABLE I.PART B BLENDS EPDMWITH POLYOLEFIN PLASTICS H Run No.

EPDM I, pts Peroxide I, pts

Peroxide, moles X 10 /100 g EPDM- Cure temp, F., max Cure time, minutes (lei, percent Hwell, percent" MIM nt 250" l". MH -l at 250 F Mnsterbatuh (EPDM), pts. l'olvpropylene I, pts ll.l5. p0 yethylene, pts

Blending temp. F., max Blending time, minutes at temp" Cale. gel, percent Actual gel, percent. Swell, percent ML-fg at 350 1L...

Elongation, percent Elongation set at break, percent llnrdness, shore A Performance factor, p.s i. 10 'l'lxtrudable injection ineldable. Press nioldable l ()il scale.

L. I). polyethylene, pts.

69 76 62 66 1. 6 4. 8 75 4. 5 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Ye Yes Yes Yes Yes Yes Ye EXAMPLE 2 In runs 24-35, summarized in Table II, the EPDM rubber employed, identified as EPDM 11, contains 70 percent ethylene, percent propylene and 5 percent 5-ethylidene-2-norbornene; the Mooney V viscosity Ml.--4 at 250F is 60, MS-4 at 250F is 23, the gel content is percent with percent swell. ln Run 24, which is included as a control, no pre-cure is imparted to the EPDM. In Runs 25, 26 and 27, the EPDM is semi-cured by hot mastication in the Banbury using as the curative the same peroxide as in Example 1'. In Runs 28-31 the substance identified in Table as accelerator l is tetramethyl thiuramidisulfide, actually a sulfur donor curative for the EPDM. ln Runs 32-35, in addition to the sulfur donor there is included an accelerator (accelerator ll), 4,4-dithiodimorpholine; Runs 33-35 further include sulfur. Runs 28- 35 also have 2 parts of zinc oxide (not shown in Table ll)'present during the pre-cure. The procedure is essentially the same as in Example 1, that is, the EPDM is hot masticated with the curatives in" the Banbury mixer to the maximum temperature shown(actual stock temperatures being 25-30F higher than the chart temperatures shown in Table 11), and continued for the time indicated. Reduced cure times are employed in Runs 28-35 because the curatives used act more rapidly. As in Example 1, 1 part of tris(nonylphenyl) phosphite antioxidant is added at the end of the semi-cure step to scavenge any residual free radicals. The gel content increases, the swelling index goes down, and the Mooney viscosity increases, as a result of the partial curing step (compare Run 24 with the other runs).

80 Parts of the thus semi-cured EPDM (designated masterbatch in Table II) is blended with 20 parts of the same polypropylene resin as used in Example l,.by hot mixing in the Banbury. The blending time and temperature (chart temperatures; actual stock temperatures 25-30F higher) are as shown in Table II. The blend is removed from the Banbury, formed into a sheet and chopped into pellets, and the material is evaluated as described in Example I.

Of the results summarized in Table II, particularly significant is the decrease in elongation set atbreak, in theblends based on semi-cured EPDM as compared to Run 24 based on EPDM that has not been semi-cured. Also significant is the increase in the performance factor." However, in Run 35, in which the cure of the EPDM'became'too far advanced in the pre-curing step, as evidenced by a high gel content of 90 percent in the trea t ed E l D M t l i eblend is no longer processable.

EXAMPLE 3 Table III summarizes Runs 36-40. The EPDM employed is the same as in Example I. Run 36 is a control, involving no semi-cure of the EPDM. In Runs 37-40, partial cure is imparted to the EPDM by hot mastication in the Banbury mixer with a peroxide curative, benzoyl peroxide (Luperco BPO), identified as peroxide II" in Table Ill, which has a half life of 0.4 hour at 212F. The procedure is as described in Example 1. The performance factor is increased in Runs 37-40, compared-to the control, Run 36, while retaining processability and reprocessability.

TABLEIII Blends of EPDM with Polypropylene Run No. 36 37 38 39 EPDM I, 118. I00 100 I00 100 100 Peroxide 1, pts. 1.0 1.25 1.67 1.86 25 Peroxide, moles X 10/l00g EPDM 4.4 5.3 7.0 7.8 Cure Temp., F 240 240 240 240 Cure Time, minutes 7 4 a 4 4 4 Gel, 3 62 61 Swell, MS-4 at 250'F 23 Y 64 67 65 67 30 Masterbatch, pts. 7 80 80 80 80 80 Polypropylene, pts. 20 20 20 20 20 Blending Temp. '5', max. 340 370 370' 370 370 Blending Time, minutes 7 2 2 4 3 Cale. Gel, k 23 55 59 69 68 Actual Gel, k 31 62 69 67 79 Swell, 13 9 8 8 8 35 I! l8 Tensile Strength, psi 830 810 910 980 1000 100% Modulus, psi 830 800 910 930 990 Elongation, 120 140 170 160 140 Elongation Set at break 4: 40 33 40 38 23 Hardness, Shore A 79 78 77 Performance Factor, psi X 10 2.5 3.4 3.9 4.1 6.1 40 Extrudable yes yes yes yes yes Injection Moldable yes yes yes yes yes Press Moldlble yes yes yes yes yes EXAMPLE 4 This example illustrates partial pre-cure of the TABLE II.-BLENDS OF EPDM WI TH POLYPROPYLENE Run Number 24 25 26 27 28 29 30 31 32 i 33 34 35 EPDM 11, pts. 100 100 100 100 100 100 100 100 100 100 1 Peroxide I, 01.5 .5 .625 .75 -3 "99"? Aeeelerutm' 1, Dis 5 1 0 1.5 2 0 5 25 .5 1.0 Aeeelerntm' 11, 01s.. 5 .25 .5 1.0 Sulfur, pts... .1 .2 .4 lure temp. l" max 360 360 360 360 360 330 360 360 360 360 360 (lure time, minutes. 7- 7 7 4 4 4 4 4 4 4 4 (.101, percent 30 47 60 67 36 42 52 59 60 68 74 Swell, percent. 35 14 13 27' 17 15 12 16 11 6 MS-4 at 250 F 23 56 67 91 43 61 74 82 78 91 Mesterbntch (EPDM) pts...- 80 80 80 80 80 80 80 80 80 80 80 80 Polypropylene, pts 20 20 20 20 20 20 20 20 20 20 20 20 Blending temp. F. ca... 340 340 340 340 340 340 340 340 340 340 340 340 Blending time, minutes 7 1 1 1 1 1 1 1 1 1 1 1 Cale. gel, percent. 43 57 67 73 48 53 61 66 67 73 78 01 Actual gel, percent 37 74 88 81 60 69 76 81 82 78 87 03 Swell, percent. 13 7 1 4 4 10 7 5 6 5 ,6 6 4 ML-5 at 350 F. 17 42 74 44 21 26 32 39 38 38 88 Tensile strength, p.s.i-... 1; 275 1,210 1, 350 1, 230 1,350 1,230 1, 340 1,340 1, 280 1,500 1,610 1,300 percent modulus, p.s.1 1,040 1,200 1,200 1, 200 1,190 1,190 1, 250 1,200 1,380 1, 000 1, 200 Elongation, percent 420 120 100 80 310 270 220 170 220 230 140 Elongation set at break, percent 15 10 13 75 55 45 23 43 43 15 23 Hardness, shore A 83 85 89 86 84 86 84 86 86 85 85 86 Performance factor, 11.5.1. 4. 5 9. 7 13. 5 12.3 5. 6 6. 0 6. 6 9.9 6. 5 8.0 11.8 8. 5 Extrudeble Yes Yes No No Yes Yes Yes Yes No Yes No No Injection m0ldable Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes No No Press modable Yes Yes Yes Yes Yes Yes Yes Yes No Yes Yes 1 Off scale.

autoclave, rather than under dynamic conditions (hot mastication in a Banbury) as in previous examples. The materials employed are as previously identified. Run 43 (Table IV) is a control in which no semi-cure is undertaken. In Runs 44-48 the EPDM rubber is mixed on a mill at room temperature with the indicated amount of the peroxide curative and the batch is then placed in an autoclave and heated at 400F. for the time indicated to effect the semi-cure statically. In some cases the thus partially cured EPDM is refined by passing it three times through a mill at 200-350F; in other cases the refining step is omitted. The increase in gel content, decrease in percent swell and increase in Mooney viscosity (in Runs 44-48) are indicative of partial crosslinking of the EPDM as a result of the static treatment with curative.

After blending with the polypropylene resin [at which time 1% of tris(nonylphenyl) phosphite is also mixed in] as in previous examples, and determination of physical properties and pro'cessability of the blends marked decrease in elongation set at break with increase in performance factor, while retaining thermoplastic reprocessability are found in Runs 44-48 of the invention as indicated in Table IV.

TABLE V Blends of EPM with Polypropylene Run No. 49 5O 51 52 53 EPM, pts. l00 I00 100 100 I00 OBSA, pts. 0.5 L0 L5 2.0 Cure Temp. "F 360 360 360 360 Cure Time, minutes 20 20 20 20 Gel, 0 66 77 82 83 Swell, 90+ 23 l4 1 l l l MS-4 at 250F 20 S0 62 75 79 Masterbatch, pts. 80 80 80 80 8O Polypropylene, pts. 20 20 20 20 20 Blending Temp. "F 360 360 360 360 360 Blending Time, minutes at temp. 7 2 2 2 2 Calc. Gel, 19 72 8] 85 85 Actual Gel, 31 66 77 80 83 Swell, l2 8 9 8 7 I ML-5 at 350F 8 4l 48 47 5Q Tensile Strength, psi 650 960 1040 N801 150 l00% Modulus, psi 450 v Elongation, 440 80 70 40 Elongation Set at break, 220 8 l0 5 l0 Hardness, Shore A 72 85 76 Performance Factor, psi X 10 1.3 9.6 7.3 9.5 6.9 Extrudable yes no no no no Injection Modable yes yes yes no no Press Moldable yes yes yes yes yes Having thus described our invention what we claim and desire to, protect by Letters Patent is:

1 A thermoplastic reprocessable blend of (A) a rub- Run No.

Yes No Yes No Gel, pcrccnt 39 2. 6 61 60 76 Swell, percent. 62 48 46 35 86 MS-4 at 250 F 37 53 Mastcrbatch, pts 80 80 80 80 80 80 Polypropylene, pts 20 20 20 20 20 20 Blending temp. F., max 360 360 360 360 360 360 Blending time, minutes 7 1 1 1 1 1 Cale, gel, percent. 23 50 40 68 67 79 Actual gel, percent 31 84 Swell, percent.

Elongation, percent 120 120 100 Elongation set at; break percent 40 28 20 15 llardncss, shore A 75 75 74 80 Performance factor, p.s.i. 10 2. 5 4. 2 6. l 7. 2 Extrudablc l Yes Yes Yes Yes injection moldsble. Yes Yes Yes Yes Press moldablo Yes Yes Yes Yes No Yes Yes Yes Yes EXAMPLE v' Table V illustrates the practice of the invention with a saturated EPM binary copolymer rubber [40% ethylene, 60 percent propylene, by weight; ML-4 at 250F is less than 20; gel content, nil (Vistalon 404)]. The curative identified. as OBSA in Table V, is p,poxybis(benzenesulfonyl-azide). No curative'is used in Run 49 (a control), In runs 50-53 the curative, in the amounts shown, is mixed with the EPM on an unheated roll mill. The EPM-curative mix is placed in an autoclave and heated to 360F, under a pressure of psi steam for 20 minutes to effect the partial cure statically. The steam pressure prevents the mixture from blowing. The resulting semi-cured EPM is removed from the autoclave and blended with the polypropylene along with 1 percent of the antioxidant, in the Banbury at the blending temperature (chart temperature) shown for the time indicated. Table V shows that the semi-cureincreases the gel content and Money viscosity, and decreases the swelling index of the EPM. In the blends, elongation set at break is greatly reduced, and "performance factor" is greatly increased.

bery copolymer of ethylene and at least one other copolymerizable monoolefin of the formula CH =CHR- linked, prior to blending to a gel content of at least 30 percent but less than 90 percent by weight measured by immersion in cyclohexane for 48 hours at 73F, and (B) an uncross-linked resinous polyolefin, the Weight ration of (A) to (B) being from l0290to 90zl0.

2. A blend as in claim 1 in which the said mono-olefin is propylene.

3. Ablend as in claim 1 in which (A) is a saturated ethylene-propylene binary copolymer.

4. A blend as in claim ,1 in which (A) is an unsaturated terpolymer of ethylene, propylene, and a nonconjugated diene.

5. A blend as in claim 4 in which the diene is dicyclopentadiene.

6. A blend as in claim 4 in which the diene is 5-ethylidene-2-norbornene.

7. A blend as in claim 1 in which the said gel content of (A) is from 40 to 85 percent.

8. A blend as in claim 1 in which the said gel content of (A) is from 55 to 85 percent. 1

9. A blend as in claim 1 in which (B) is selected from the group consisting of polyethylene and polypropylene. Y

10. A blend as in claim 1 in which (B) is polyethylene.

11. A blend as in claim in which the polyethylene has a density of 0.910 to 0.925 g/cc.

12. A blend as in claim 10 in which the polyethylene has a density of 0.926 to 0.940 g/cc.

13. A blend as in claim 10 in which the polyethylene has a density of 0.941 to 0.965 g/cc.

14. A blend as in claim 1 in which (B) is polypropylene.

15. A blend as in claim 14 in which the polypropylene is isotactic.

16. A blend as in claim 1 in which the weight ratio of (A) to (B) is from 50:50 to 90:10.

17. A blend as in claim 1 in which theweight ratio of (A) to (B) is from 60:40 to 80:20. 18. A blend as in claim 1 in which (A) is semi-cured with a peroxide curative. I I

19. A blend as in claim 18 in which (A) is saturated ethylene-propylene binary copolymer.

20. A blend as in claim 18 in which (A) is an unsaturated ethylene-propylene-non-conjugated diene terpolymer.

21. A blend as in claim 18 in whichthe peroxide cu rative is 2,5-bis(tert.-butylperoxy)-2,5- dimethylhexane. I

22. A blend as in claim 18 in which the peroxide curative is benzoyl peroxide.

23. A blend as in claim 1 in which (A) is semi-cured with an azide curative.

24. A blend as in claim 23 in which the azide curative is p,p'-oxybis(benzenesulfonylazide).

25. A blend as in claim 1 in which (A) is unsaturated ethylene-propylene-non-conjugated diene terpolymer semi-cured with a sulfur curative.

26. A thermoplastic reprocessable blend of A. a monoolefin copolymer rubber selected from the group consisting of saturated ethylene-propylene binary copolymer rubber and unsaturated ethylen e-propylene-non-conjugated diene terpolymerrubber, partially crosslinked, prior to blending, to a gel content of from 40 to 85 percent, measured by immersion in cyclohexane for 48 hours at 73F., the percent swell of the said partially cross-linked rubber being 10m 70 percent less than the percent swell prior to cross-linking of the rubber, said partially cross-linked rubber being capable of forming a coherent band on a roll mill, and

B. an uncross-linked resinous polyolefin selected from the group consisting of polyethylene and polypropylene, the weight ratio of (A) to (B) being from 69:40 to 80:20, the said blend, when formed into a molded test specimen without further crosslinking, having a performance factor (defined as the value obtained by multiplying the tensile strength in psi by the ultimate elongation in percent and dividing by the elongation set in percent)being at least percent in excess of the performance factor of an otherwise identical blend containing the same rubber without partial cross-linking, whereby the said blend containing the partially cross-linked rubber has the characteristics of a thermoplastic elastomer.

27. A method of making a thermoplastic reprocessable blend comprising in combination the steps of Y a. providing (A) a rubbery copolymer of ethylene and at least one other copolymerizable monoolefin of the formula CH =CHR where R is'an alkyl radical having from one to 12 carbon atoms, with or without at least one copolymerizable polyene,

b. semi-curing the said rubbery copolymer until it has a gel content, measured'by immersion in cyclohexane for 48 hours at 73F, at least 10 percent higher than the gel content of the said rubbery copolymer prior to said semi-cure, but less than 90%,

- c. providing (13) an uncross-linked resinous polyolefin, and

d. uniformly blending (A) and (B) at a temperature in excess of the softening temperature of (B), the weight ratio of (A) to (B) being from 10:90 to 90:10.

28. A method as in claim 27 in which the action of the curative in step (b) is substantially exhaused.

29. A method as in claim 27 in which the said semicuring step (b) is carried out by heating the said rubbery copolymer (A) at curing temperature in admixture with a curative for said rubbery copolymer until the said gel content is at least 20 percent higher than the gel content of the; starting rubbery copolymer.

30. A method as in claim 27 in which the said semicuring step (b) is carried out by heating the said rubberycopolymer (A) at curing temperature'in admixture with a curativeforsaid rubbery copolymer until thesaid gel content is at least 30 percent higherthan the gel content of the starting rubbery copolymer.

31..A method as inclaim 30 in which the said gel content after the semi-curing step (b) is within the 35. A method as'in claimi33 in which the peroxide curative is'benzoylperoxide.

36. A method asin claim.32 in which the curativev is an azide curative. t v

37. A method as in claim36 in which theazide curative is,p,p'.-oxybis (benzenesulfonylazide).

38. A method'as in'claim 32 in which (A) is an unsat urated ethylene propyleneman-conjugated diene terpolymer rubber and the said "curative is a sulfur curative.

39. A method as in claim 32 in which the semi-curing step (b) is carried out under dynamic conditions while masticating the mixture of rubbery copolymer and curative. v

40. A method as in claim 32 in which the semi-curing. step (b)is carried out under static conditions.

41. A method of making a' thermoplastic reprocessableblend comprising in combination the steps of I a. providing (A) a monoolefin copolymer rubber selected from the group consisting of saturated ethylene propylene binary copolymer rubber and unsaturated ethylene-propylene non-conjugated diene terpolymerrubber,

b. heating the said rubbery 'copolymerat curing tembery copolymer until the gel content of the copolymer, measured by immersion in cyclohexane at 73F. is within the range of from 40 to 85 percent,

the percent swell after said heating being percent to 70 percent less than prior to said heating, the thus-treated rubbery copolymer being in a semi-cured thermoplastic state and capable of being formed into a coherent band on a roll mill,

c. providing (B) an uncross-linked resinous polyoletin, and

d. uniformly blending (A) and (B) by masticating at a temperature in excess of the softening temperature of (B), the weight ratio of (A) to (B) being from 60:40 to 80:20, the resulting blend being a thermoplastic elastomeric composition.

42. A method as in claim 41 in which the action of the curative in step (b) is substantially exhausted and thereafter an antioxidant is added to scavenge any residual free radicals.

43. A method as in claim 42 in which step (b) is carried out while masticating the mixture of rubbery copolymer and curative in a heated internal mixer.

44. A method as in claim 42 in which step (b) is carried out statically in a heated autoclave.

45. A method of making a thermoplastic elastomeric shaped article comprising carrying out the steps of claim 42, and thereafter shaping the blend into a desired shape without further cure, whereby the shaped blend can be reprocessed.

mg um'mn S'IA'I'ES PATENT, omen CERTIFICATE OF CORRECTION mm m 3,758,643 mt Septemberll; 1943 Invmmfl.) William K. Fischer It in certified that error appura in the abova-idntifiud plant and that aid Letters Patent an hereby corrected as shown bnlow:

Column 16, line 56, for fration" read -ra-tio--.

Column 17, line 57, for "692 40" read '--60:40--.

Column 18, line 20, for "exhaused" read '--exhausted--; line 37, for "(a)" read --(A)--.

Signed and sealed this 16th day of A ri1" 1971;.

(SEAL) Attest:

EDWARD I-LFLETCHERJH. C. MARSHALL DANN Qommissioner of Patents Attesting Officer 

2. A blend as in claim 1 in which the said mono-olefin is propylene.
 3. A blend as in claim 1 in which (A) is a saturated ethylene-propylene binary copolymer.
 4. A blend as in claim 1 in which (A) is an unsaturated terpolymer of ethylene, propylene, and a non-conjugated diene.
 5. A blend as in claim 4 in whiCh the diene is dicyclopentadiene.
 6. A blend as in claim 4 in which the diene is 5-ethylidene-2-norbornene.
 7. A blend as in claim 1 in which the said gel content of (A) is from 40 to 85 percent.
 8. A blend as in claim 1 in which the said gel content of (A) is from 55 to 85 percent.
 9. A blend as in claim 1 in which (B) is selected from the group consisting of polyethylene and polypropylene.
 10. A blend as in claim 1 in which (B) is polyethylene.
 11. A blend as in claim 10 in which the polyethylene has a density of 0.910 to 0.925 g/cc.
 12. A blend as in claim 10 in which the polyethylene has a density of 0.926 to 0.940 g/cc.
 13. A blend as in claim 10 in which the polyethylene has a density of 0.941 to 0.965 g/cc.
 14. A blend as in claim 1 in which (B) is polypropylene.
 15. A blend as in claim 14 in which the polypropylene is isotactic.
 16. A blend as in claim 1 in which the weight ratio of (A) to (B) is from 50:50 to 90:10.
 17. A blend as in claim 1 in which the weight ratio of (A) to (B) is from 60:40 to 80:20.
 18. A blend as in claim 1 in which (A) is semi-cured with a peroxide curative.
 19. A blend as in claim 18 in which (A) is saturated ethylene-propylene binary copolymer.
 20. A blend as in claim 18 in which (A) is an unsaturated ethylene-propylene-non-conjugated diene terpolymer.
 21. A blend as in claim 18 in which the peroxide curative is 2, 5-bis(tert.-butylperoxy)-2,5-dimethylhexane.
 22. A blend as in claim 18 in which the peroxide curative is benzoyl peroxide.
 23. A blend as in claim 1 in which (A) is semi-cured with an azide curative.
 24. A blend as in claim 23 in which the azide curative is p,p''-oxybis(benzenesulfonylazide).
 25. A blend as in claim 1 in which (A) is unsaturated ethylene-propylene-non-conjugated diene terpolymer semi-cured with a sulfur curative.
 26. A thermoplastic reprocessable blend of A. a monoolefin copolymer rubber selected from the group consisting of saturated ethylene-propylene binary copolymer rubber and unsaturated ethylene-propylene-non-conjugated diene terpolymer rubber, partially cross-linked, prior to blending, to a gel content of from 40 to 85 percent, measured by immersion in cyclohexane for 48 hours at 73*F., the percent swell of the said partially cross-linked rubber being 10 to 70 percent less than the percent swell prior to cross-linking of the rubber, said partially cross-linked rubber being capable of forming a coherent band on a roll mill, and B. an uncross-linked resinous polyolefin selected from the group consisting of polyethylene and polypropylene, the weight ratio of (A) to (B) being from 69:40 to 80:20, the said blend, when formed into a molded test specimen without further cross-linking, having a performance factor (defined as the value obtained by multiplying the tensile strength in psi by the ultimate elongation in percent and dividing by the elongation set in percent) being at least 20 percent in excess of the performance factor of an otherwise identical blend containing the same rubber without partial cross-linking, whereby the said blend containing the partially cross-linked rubber has the characteristics of a thermoplastic elastomer.
 27. A method of making a thermoplastic reprocessable blend comprising in combination the steps of a. providing (A) a rubbery copolymer of ethylene and at least one other copolymerizable monoolefin of the formula CH2 CHR where R is an alkyl radical having from one to 12 carbon atoms, with or without at least one copolymerizable polyene, b. semi-curing the said rubbery copolymer until it has a gel content, measured by immersion in cyclohexane for 48 hours at 73*F., at least 10 percent higher than the gel content of the said rubbery copolymer prior to said seMi-cure, but less than 90%, c. providing (B) an uncross-linked resinous polyolefin, and d. uniformly blending (A) and (B) at a temperature in excess of the softening temperature of (B), the weight ratio of (A) to (B) being from 10:90 to 90:10.
 28. A method as in claim 27 in which the action of the curative in step (b) is substantially exhaused.
 29. A method as in claim 27 in which the said semi-curing step (b) is carried out by heating the said rubbery copolymer (A) at curing temperature in admixture with a curative for said rubbery copolymer until the said gel content is at least 20 percent higher than the gel content of the starting rubbery copolymer.
 30. A method as in claim 27 in which the said semi-curing step (b) is carried out by heating the said rubbery copolymer (A) at curing temperature in admixture with a curative for said rubbery copolymer until the said gel content is at least 30 percent higher than the gel content of the starting rubbery copolymer.
 31. A method as in claim 30 in which the said gel content after the semi-curing step (b) is within the range of from 40 to 85 percent.
 32. A method as in claim 30 in which the said rubbery copolymer (a) after the semi-curing step (b) has percent swell at least 8% less than the percent swell prior to the semi-cure.
 33. A method as in claim 32 in which the curative is a peroxide curative.
 34. A method as in claim 33 in which the peroxide curative is 2, 5-bis(tert.-butylperoxy)-2,5-dimethylhexane.
 35. A method as in claim 33 in which the peroxide curative is benzoyl peroxide.
 36. A method as in claim 32 in which the curative is an azide curative.
 37. A method as in claim 36 in which the azide curative is p,p''-oxybis (benzenesulfonylazide).
 38. A method as in claim 32 in which (A) is an unsaturated ethylene-propylene-non-conjugated diene terpolymer rubber and the said curative is a sulfur curative.
 39. A method as in claim 32 in which the semi-curing step (b) is carried out under dynamic conditions while masticating the mixture of rubbery copolymer and curative.
 40. A method as in claim 32 in which the semi-curing step (b) is carried out under static conditions.
 41. A method of making a thermoplastic reprocessable blend comprising in combination the steps of a. providing (A) a monoolefin copolymer rubber selected from the group consisting of saturated ethylene propylene binary copolymer rubber and unsaturated ethylene-propylene-non-conjugated diene terpolymer rubber, b. heating the said rubbery copolymer at curing temperature in admixture with a curative for said rubbery copolymer until the gel content of the copolymer, measured by immersion in cyclohexane at 73*F. is within the range of from 40 to 85 percent, the percent swell after said heating being 10 percent to 70 percent less than prior to said heating, the thus-treated rubbery copolymer being in a semi-cured thermoplastic state and capable of being formed into a coherent band on a roll mill, c. providing (B) an uncross-linked resinous polyolefin, and d. uniformly blending (A) and (B) by masticating at a temperature in excess of the softening temperature of (B), the weight ratio of (A) to (B) being from 60:40 to 80:20, the resulting blend being a thermoplastic elastomeric composition.
 42. A method as in claim 41 in which the action of the curative in step (b) is substantially exhausted and thereafter an antioxidant is added to scavenge any residual free radicals.
 43. A method as in claim 42 in which step (b) is carried out while masticating the mixture of rubbery copolymer and curative in a heated internal mixer.
 44. A method as in claim 42 in which step (b) is carried out statically in a heated autoclave.
 45. A method of making a thermoplastic elastomeric shaped article comprising carrying out the steps of claim 42, and thereafter shaping the bleNd into a desired shape without further cure, whereby the shaped blend can be reprocessed. 